Physical Review E
Order, Transition, Films
Free-standing monodomain thick films of three liquid crystalline compounds were examined by x-ray scattering. These compounds exhibit a unique enantiotropic crystal-B-hexatic-B-smectic-A phase sequence with no evidence of herringbone order. The hexatic order parameter Cg changes in the hexatic phase with critical exponent beta=0.15+/-0.03. Temperature dependence of the in-plane positional order correlation length suggests a strongly first-order hexatic-B to crystal-B phase transition with indiscernible enthalpy change.
Gorecka, Ewa; Chen, Li; Pyzuk, Wieslaw; Krowczynski, Adam; and Kumar, Satyendra (1994). X-Ray Studies of the Hexatic Phase in Liquid-Crystals With a Crystal-B-Hexatic-B-Smectic-A Phase Sequence. Physical Review E 50(4), 2863-2867. doi: 10.1103/PhysRevE.50.2863 Retrieved from https://digitalcommons.kent.edu/phypubs/74